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Theorem
Any number of the form  
\[4k+3\]
  is divisible by a prime number of this form.
Proof
The Division Algorithm tells us that any integer is one of the forms  
\[4q, \; 4q+1, \; 4q+2, \; 4q+3\]
.  
\[4q\]
  and  
\[4q+2\]
  are even so for  
\[q \ge 1\]
  these numbers are composite.  
\[4k+3\]
  is odd so not divisible by primes of the form  
\[4q\]
  or  
\[4q+2\]
.
Suppose then that it is only divisible by primes of the form  
\[4q+1\]
. But then since  
\[(4s+1)(4q+1)=4(4sq+s+q)+1\]
  the number would then be of this form (and not  
\[4k+3\]
), so by elimination,  
\[4k+3\]
  must be divisible by a prime of this form.