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A vector space has not quite as much to do with vectors as you might think. A wide range of sets of things can be considered as vector spaces. Polynomials are usually considered as functions, but we cab treat them as vectors. This is because for a polynomial  
\[p(x)=a_0 +a_1 x+a_2 x^2 +a_3x^3+...+a_nx^n\]
  all the powers of  
\[x\]
  are linearly independent, so that for example  
\[x^2\]
  cannot be expressed in terms of higher or lower powers of  
\[x\]
.
To express a polynomial of degree at most two as a vector,
write 1 as  
\[\begin{pmatrix}1\\0\\0\end{pmatrix}\]

write  
\[x\]
  as  
\[\begin{pmatrix}0\\1\\0\end{pmatrix}\]

write  
\[x^2\]
  as  
\[\begin{pmatrix}0\\0\\1\end{pmatrix}\]

The polynomial  
\[2-3x+x^2\]
  can then be written as  
\[\begin{pmatrix}2\\-3\\1\end{pmatrix}\]
.
All the usual rules of addition and scalar multiplication of vectors apply, so we can consider polynomials - of any degree - as a vector space.