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A linear transformation is one to one and onto if and only if it has an inverse.
We can represent a rotation in  
\[\mathbb{R}^n\]
  by a matrix  
\[R( \theta )\]
  where  
\[R\]
  means rotation and  
\[\theta\]
  means a rotation anticlockwise through an angle  
\[\theta\]
.
The inverse to this transformation is the rotation  
\[R(- \theta )\]
, the rotation about the same axis through the same angle in the opposite direction. Hence rotations in  
\[\mathbb{R}^n\]
  are one to one and onto.
Reflections in  
\[\mathbb{R}^n\]
  are also one to one and onto since the inverse of any reflection represented by a matrix  
\[q ( \theta )\]
  is  
\[q (- \theta )\]

Since reflections are self inverse, they are also one to one and onto.